Rheology V3

Rheology: Theory and Applications, Volume 3 is a collection of articles contributed by experts in the field of rheology - the science of deformation and flow.

This volume is composed of specialized chapters on the application of normal coordinate analysis to the theory of high polymers; principles of rheometry; and the rheology of cross-linked plastics, poly electrolytes, latexes, inks, pastes, and clay. Also included are a series of technological articles on lubrication, spinning, molding, extrusion, and adhesion and a survey of the general features of industrial rheology.

Materials scientists, geophysicists, and engineers will find the book very insightful.

Contenu

Preface
Contributors to Volume 3
Contents of Volumes 1 and 2

1. The Normal-Coordinate Method for Polymer Chains in Dilute Solution
   I. Introduction
   II. The Elastic Dumbbell
   III. The Elastic Chain
   Nomenclature
2. The Principles of Rheometry
   I. Introduction
   II. Capillary Viscometers
   III. Rotating Coaxial Cylinder Viscometers
   IV. Oscillating Coaxial Cylinder Viscometers
   V. Disk Viscometers
   VI. Concentric Sphere Viscometers
   VII. Cone and Plate, Double Cone, and Conicylindrical Viscometers
   VIII. Oscillating Plate Viscometers
   IX. Falling Sphere Viscometers
   X. Parallel Plate Plastometers
   XI. Coaxial Cylinder Viscometers with Axial Motion
   Nomenclature
3. Viscosity of Suspensions of Electrically Charged Particles and Solutions of Polymeric Electrolytes
   I. Introduction
   II. Simple Strong Electrolytes
   III. Electroviscous Effects with Impermeable Macromolecular Particles
   IV. Comparison of Theory with Experiment for the First Electroviscous Effect
   V. The Second Electroviscous Effect
   VI. Electroviscous Effects in the Close Approach of Macroscopic Bodies and in Sedimentation
   VII. The Third Electroviscous Effect
   VIII. General Expression for the Electroviscous Effects
   Nomenclature
4. The Rheology of Latex
   I. Introduction
   II. Literature Resumé
   III. Experimental Determination of Flow Behavior
   IV. Dependency of Latex Flow on Shearing Stress
   V. Dependence of Latex Flow on Concentration
   VI. Effect of Particle Size and Size Distribution
   VII. Effect of Temperature
   VIII. Effect of Electrolytes
   IX. Some Unsolved Problems in Latex Rheology
   Nomenclature
5. The Rheology of Printing Inks
   I. The Role of Printing Inks
   II. Rheological Requirements of Printing Inks
   III. Ink Production
   IV. Printing
   V. Viscometric Study of Printing Inks
   VI. Tack and Related Phenomena
   Nomenclature
6. Rheology of Pastes and Paints
   I. Introduction
   II. Instruments
   III. Flow Measurements
   IV. Physical Considerations
   V. Product Evaluation
   Nomenclature
7. Atomistic Approach to the Rheology of Sand-Water and of Clay-Water Mixtures
   I. Analysis of the Problem
   II. Some Unique Properties of Water
   III. Surface Properties of Solids Containing Cations of High Charge and Low Polarizability (Quartz, Clay)
   IV. The Interaction of Minerals with Water
   V. Summary
8. The Rheology of Inorganic Glasses
   I. Introduction : The Importance of the Viscosity of Glass for Its Manufacture
   II. Methods of Measuring the Viscosity of Glass
   III. Principles Governing the Polymerization of Ionic Compounds and Formation of Viscous Liquids
   IV. Factors Determining the Rheological Properties of Glass
   V. Interpretation of the Viscosity of Some Simple Experimental Glasses of Systematically Varied Compositions
   VI. Viscosities of Some Commercial Glasses
   VII. Flow Processes within a Rigid Glass
   VIII. Summary and Conclusions
9. The Rheology of Concrete
   I. Introduction
   II. Fresh Cement Paste
   III. Set Cement
   IV. Mortar
   V. Concrete
   VI. Reinforced Concrete
   Nomenclature
10. The Deformation of Crystalline and Cross-Linked Polymers
    I. Introduction
    II. Polyethylene
    III. Hard Rubber: A Highly Polar, Cross-Linked Polymer
    IV. Polyamides: Polar Chain Polymers Examined for Both Long and Short Range Behavior
    V. Conclusion
    Nomenclature
11. The Viscosity and Elasticity of Interfaces
    I. Interfacial Viscosity
    II. Interfacial Elasticity
    III. Significance of Interfacial Viscosity and Elasticity
    Nomenclature
12. Rheology of Lubrication and Lubricants
    I. Fluid Lubricants
    II. Gelled Lubricants
    III. Flow Phenomena in Boundary Lubrication
    Nomenclature
13. The Rheology of Adhesion
    I. Introduction
    II. Application of Adhesives
    III. Tackiness
    IV. Time of Set
    V. Final Strength
    VI. Summary
    Nomenclature
14. Rheology in Molding
    I. Introduction
    II. The Injection Molding Machine
    III. The Injection Molding Cycle
    IV. Filling the Mold
    V. Packing in the Mold
    VI. Discharge and Sealing
    VII. Sealed Cooling
    VIII. Cycle Time
    Nomenclature
    General Bibliography
15. Rheology of Spinning
    I. Introduction
    II. Description of the Problem
    III. Discussion of the Physical Characteristics of Spinnable Materials
    IV. Flow under Fiber-Forming Conditions
    V. Evaluation Techniques
    VI. Interpretation of Phenomena Accompanying the Fiber Formation
    VII. Summarizing Discussion of Present Knowledge of the Various Rheological Problems Involved in Spinning
    VIII. Appendix
    Nomenclature
16. Theory of Screw Extruders
    I. Introduction
    II. Flow and Power Formulas
    III. Operating Equations for Melt Extrusion
    IV. Extrusion of Non-Newtonian Melts
    V. Plasticating Extrusion
    Nomenclature
    Author Index
    Subject Index