Progress in Physical Chemistry Volume 4

This fourth volume of the series "Progress in Physical Chemistry" is a collection of mini-review articles written by those who were project leaders and members of the Collaborative Research Centre (SFB) 458 of the German Research Foundation (DFG). The articles are based on ten years of intense coordinated research and report particularly on the scientific progress made at SFB 458 since 2005. Their common theme is the study of ionic motion in disordered materials over wide scales in space and time. The mini reviews thus address key questions in the rapidly developing field of SOLID STATE IONICS, a discipline which has its roots in the physics and chemistry of solids and is now a thriving branch of materials science and engineering. In the materials studied, the dynamics of the mobile ions are de-termined by disorder and interaction. This complicated many-particle problem constitutes an area of basic research in its own right. At SFB 458, it has been tackled on complementary routes, i.e., by synthesis of new disordered electrolytes, by advanced experimental techniques and by numerical simulations and model concepts. Substantial progress has thus been made in developing a coherent view and a new understanding of the ionic motion in materials with disordered structures.

Contenu

Front Matter -- A Synthesis and Characterisation of New Materials Projects A2, A3 and A5 of SFB 458 -- A Synthesis and Characterisation of New Materials Projects A2, A3 and A5 of SFB 458 -- Salt-in-Polymer Electrolytes for Lithium Ion Batteries Based on Organo-Functionalized Polyphosphazenes and Polysiloxanes -- A Synthesis and Characterisation of New Materials Projects A2, A3 and A5 of SFB 458 -- Lithium-Transition Metal-Tetrelides - Structure and Lithium Mobility -- A Synthesis and Characterisation of New Materials Projects A2, A3 and A5 of SFB 458 -- Silver(I)-(poly)chalcogenide Halides - Ion and Electron High Potentials -- B Experimental Investigation of Disorder and Ionic Motion Projects B5, A6/B6, B7, B9, B10, B12, B14, B15, B16 and B17 of SFB 458 -- B Experimental Investigation of Disorder and Ionic Motion Projects B5, A6/B6, B7, B9, B10, B12, B14, B15, B16 and B17 of SFB 458 -- NMR Multi-Time Correlation Functions of Ion Dynamics in Solids -- B Experimental Investigation of Disorder and Ionic Motion Projects B5, A6/B6, B7, B9, B10, B12, B14, B15, B16 and B17 of SFB 458 -- Mechanisms of Ion Conduction in Polyelectrolyte Multilayers and Complexes -- B Experimental Investigation of Disorder and Ionic Motion Projects B5, A6/B6, B7, B9, B10, B12, B14, B15, B16 and B17 of SFB 458 -- Short and Medium Range Order in Ion-Conducting Glasses Studied by Modern Solid State NMR Techniques -- B Experimental Investigation of Disorder and Ionic Motion Projects B5, A6/B6, B7, B9, B10, B12, B14, B15, B16 and B17 of SFB 458 -- Nonlinear DC and Dispersive Conductivity of Ion Conducting Glasses and Glass Ceramics -- B Experimental Investigation of Disorder and Ionic Motion Projects B5, A6/B6, B7, B9, B10, B12, B14, B15, B16 and B17 of SFB 458 -- Dynamics of Network Formers and Modifiers in Mixed Cation Silicate Glasses -- B Experimental Investigation of Disorder and Ionic Motion Projects B5, A6/B6, B7, B9, B10, B12, B14, B15, B16 and B17 of SFB 458 -- The Use of Radiotracer Diffusion to Investigate Ionic Transport in Polymer Electrolytes: Examples, Effects, and Their Evaluation -- B Experimental Investigation of Disorder and Ionic Motion Projects B5, A6/B6, B7, B9, B10, B12, B14, B15, B16 and B17 of SFB 458 -- Local Li Cation Coordination and Dynamics in Novel Solid Electrolytes -- B Experimental Investigation of Disorder and Ionic Motion Projects B5, A6/B6, B7, B9, B10, B12, B14, B15, B16 and B17 of SFB 458 -- Transport Mechanisms of Ions in Graft-Copolymer Based Salt-in-Polymer Electrolytes -- B Experimental Investigation of Disorder and Ionic Motion Projects B5, A6/B6, B7, B9, B10, B12, B14, B15, B16 and B17 of SFB 458 -- Nanoanalysis and Ion Conductivity of Thin Film Battery Materials -- B Experimental Investigation of Disorder and Ionic Motion Projects B5, A6/B6, B7, B9, B10, B12, B14, B15, B16 and B17 of SFB 458 -- Ion Jump Dynamics in Nanoscopic Subvolumes Analyzed by Electrostatic Force Spectroscopy -- C Simulation and Development of Model Concepts Projects C1/C5 and C2 of SFB 458 -- C Simulation and Development of Model Concepts Projects C1/C5 and C2 of SFB 458 -- Theoretical Description of Ion Conduction in Disordered Systems: From Linear to Nonlinear Response -- C Simulation and Development of Model Concepts Projects C1/C5 and C2 of SFB 458 -- First and Second Universalities: Expeditions Towards and Beyond -- Back Matter