Perovskites and Related Mixed Oxides

In zwei Bänden dieses ausführlichen Nachschlagewerks erläutern die Autoren in ausgewogener Weise Potenzial und Herausforderungen beim Einsatz dieser Materialien und bieten neue Perspektiven für Forschung und Entwicklung, sowohl im akademischen als auch im industriellen Bereich.

Auteur
Pascal Granger is Head of the Catalysis and Solid State Chemistry Department at the University of Lille, France. He obtained his PhD in Applied Chemistry from the University of Poitiers, France, and did postdoctoral research at the University of Lille before he became Full Professor there in 2003. Pascal Granger investigates the mechanisms and kinetics of heterogeneous catalytic reactions and is involved in the development of spectroscopic characterizations of DeNOx and DeN2O abatement processes. He is author and co-author of 85 publications in refereed international journals and of one book.

Vasile I. Parvulescu is Director of the Department of Organic Chemistry, Biochemistry and Catalysis at the University of Bucharest, Romania. He received his PhD in Chemistry from the University of Bucharest for a work on the selectivity of bi- and multi-metal catalysts in hydrogenation of aromatic hydrocarbons. After several years as senior researcher at the Institute for Non-Ferrous and Rare Metals in Bucharest, he rejoined the University of Bucharest in 1992 where he became full professor in 1999. His current interest concerns the study of heterogeneous catalysts for green and fine chemistry as well as for environmental protection. He authored more than 240 papers, 25 patents and 4 books.

Serge Kaliaguine is Professor in the Department of Chemical Engineering at the University of Laval in Quebec, Canada. He has developed a strong expertise in the fields of zeolites and mesoporous molecular sieves and perovskites and other mixed oxides for which he developed a novel reactive grinding technology for industrial applications. He is also involved in the preparation of composite proton conducting membranes. Serge Kaliaguine is co-author of more than 300 peer-reviewed publications in the field of applied chemistry, chemical engineering and polymer chemistry.

Wilfrid Prellier is Senior CNRS Researcher in the CRISMAT Laboratory at the University of Caen, France. After his PhD in Chemistry he held postdoctoral positions at the University of Orsay, France, and at the University of Maryland, USA. His fields of interest are thin film growth and material physics of complex oxides, oxide heterostructures and multilayers. He is author and co-author of more than 180 publications in refereed international journals and gave more than 50 invited talks at international conferences. In 2013 Wilfrid Prellier received the prize of the Solid State Division from the French Chemical Society.

Résumé
This comprehensive handbook and ready reference details all the main achievements in the field of perovskite-based and related mixed-oxide materials. The authors discuss, in an unbiased manner, the potentials as well as the challenges related to their use, thus offering new perspectives for research and development on both an academic and industrial level.
The first volume begins by summarizing the different synthesis routes from molten salts at high temperatures to colloidal crystal template methods, before going on to focus on the physical properties of the resulting materials and their related applications in the fields of electronics, energy harvesting, and storage as well as electromechanics and superconductivity. The second volume is dedicated to the catalytic applications of perovskites and related mixed oxides, including, but not limited to total oxidation of hydrocarbons, dry reforming of methane and denitrogenation. The concluding section deals with the development of chemical reactors and novel perovskite-based applications, such as fuel cells and high-performance ceramic membranes. Throughout, the contributions clearly point out the intimate links between structure, properties and applications of these materials, making this an invaluable tool for materials scientists and for catalytic and physical chemists.

Contenu

List of Contributors XXIII

Preface XXXV

Volume 1 Part One Rational Design and Related Physical Properties 1

1 From Solid-State Chemistry to Soft Chemistry Routes 3
Vicente Rives

1.1 Introduction 3

1.2 Processes Involving Solids 4

1.2.1 The Ceramic Method 4

1.2.2 Microwave Synthesis 5

1.2.3 Self-Propagating High-Temperature Synthesis (SHS) 6

1.2.4 The Precursor Method 6

1.2.5 Hydrothermal Synthesis 7

1.2.6 High-Pressure Methods 8

1.2.7 Mechanochemistry 8

1.2.8 Other Methods Starting from Solids 9

1.3 Processes Involving Liquids 9

1.3.1 Flux Method 9

1.3.2 Molten Salt Electrolysis 10

1.3.3 SolGel 10

1.3.4 Spray Drying (SD) and Related Methods 13

1.3.4.1 Freeze-Drying 14

1.3.4.2 SprayFreeze-Drying 14

1.3.5 Molecular Self-Assembling 14

1.3.6 Other Methods Starting from Liquid Reactants or Solutions 15

1.3.6.1 Ionic Liquids 15

1.3.6.2 The Gel Combustion Method 15

1.3.6.3 Sonication 15

1.3.6.4 Reverse Microemulsion 15

1.4 Processes Involving Gases or Vapors 16

1.4.1 Gas Flame Combustion 16

1.4.2 Chemical Vapor Deposition (CVD) 16

1.5 Single Crystals 16

1.6 Nanoparticles 18

1.7 Films 19

1.8 Conclusions 19

References 20

2 Mechanochemistry 25
Houshang Alamdari and Sébastien Royer

2.1 Introduction 25

2.2 Historical Development 25

2.3 Terminology 28

2.4 Mechanosynthesis Process 29

2.5 Milling Facilities 32

2.5.1 Spex Mills 32

2.5.2 Planetary Mills 34

2.5.3 Attrition Mills 35

2.5.4 Zoz Mills 36

2.6 Mechanosynthesis of Perovskites 37

2.6.1 Looking for an Alternative Route to Synthesize New Compositions 38

2.6.2 Lowering Sintering Temperature 38

2.6.3 Reducing Crystallite Size and Modifying Particle Morphology 39

2.6.4 Increasing Specific Surface Area 40

2.7 Concluding Remarks 42

References 43

3 Synthesis and Catalytic Applications of Nanocast Oxide-Type Perovskites 47
Mahesh Muraleedharan Nair and Serge Kaliaguine

3.1 Introduction 47

3.2 Perovskite Structure 48

3.3 Evolution of Perovskite Synthesis 49

3.4 General Principles of Nanocasting 51

3.5 Nanocasting of Perovskites 52

3.6 Catalytic Studies 56

3.6.1 Total Oxidation of Methane 56

3.6.2 Reduction of NO to N2 57

3.6.3 Chemical Looping Combustion 58

3.6.4 Total Oxidation of Methanol 59

3.6.5 Dry Reforming of Methane 60

3.7 Conclusions and Perspectives 63

References 64

4 Aerosol Spray Synthesis of Powder Perovskite-Type Oxides 69
Davide Ferri, Andre Heel, and Dariusz Burnat

4.1 Introduction 69

4.2 Flame Spray Synthesis 71

4.2.1 Methane Flame 72

4.2.2 Acetylene Flame 75

4.3 Flame Hydrolysis 80

4.4 Ultrasonic Spray Synthesis 82

4.4.1 General Particle Properties 83

4.4.2 Citric Acid Assisted Synthesis 85

References 87

5 Application of Microwave and Ultrasound Irradiation in the Synthesis of Perovskite-Type Oxides ABO3 91
Juan C. Colmenares, Agnieszka Magdziarz, and Pawe? Lisowski

5.1 Introduction 91

5.2 Microwave Methodology 92

5.2.1 Basic Concepts of Microwave Chemistry 92

5.2.2 Microwave Heating in Combination with Traditional Synthesis Methods 93

5.2.2.1 Microwave-Assisted Hydrothermal Method (HTMW) 93

5.2.2.2 Other Microwave-Assisted Methods 100

5.3 Ultrasound Methodology 101 5.3.1 Basic Concepts of Ultrasound Chemistry 101</p&...