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The third edition of this book on name reactions contains major improvements over the previous edition. In addition to updated references, each reaction is now supplemented with two to three representative examples in synthesis to showcase its synthetic utility. Biographical sketches for the chemists who discovered or developed those name reactions have been included. Furthemore, the subject index is significantly expanded.
This book differs from others on name reactions in organic chemistry by focusing on their mechanisms. It covers over 300 classical as well as contemporary name reactions. Each reaction is delineated by its detailed step-by-step, electron-pushing mechanism, supplemented with the original and the latest references, especially review articles. Thus, it is not only an indispensable resource for senior undergraduate and graduate students for learning and exams, but also a good reference book for all chemists interested in name reactions.
Many chemists collect named and unnamed reactions and their mechanisms
Will make this time-consuming effort redundant
Gives the earliest and latest references to these name reactions
Gives representative examples in synthesis
Includes supplementary material: sn.pub/extras
Contenu
Abnormal Claisen rearrangement.- Alder ene reaction.- Allan-Robinson reaction.- Alper carbonylation.- Amadori glucosamine rearrangement.- Angeli-Rimini hydroxamic acid synthesis.- ANRORC mechanism.- Arndt-Eistert homologation.- Baeyer-Drewson indigo synthesis.- Baeyer-Villiger oxidation.- Baker-Venkataraman rearrangement.- Bamberger rearrangement.- Bamford-Stevens reaction.- Bargellini reaction.- Bartoli indole synthesis.- Barton decarboxylation reaction.- Barton-McCombie deoxygenation reaction.- Barton nitrite photolysis.- Baylis-Hillman reaction.- Beckmann rearrangement.- Beirut reaction.- Benzilic acid rearrangement.- Benzoin condensation.- Bergman cyclization.- Biginelli pyrimidone synthesis.- Birch reduction.- Bischler-Möhlau indole synthesis.- Bischler-Napieralski reaction.- Blaise reaction.- Blanc chloromethylation reaction.- Boekelheide reaction.- Boger pyridine synthesis.- Boord reaction.- Borsche-Drechsel cyclization.- Boulton-Katritzky rearrangement.- Bouveault aldehyde synthesis.- Bouveault-Blanc reduction.- Boyland-Sims oxidation.- Bradsher reaction.- Brook rearrangement.- Brown hydroboration reaction.- Bucherer carbazole synthesis.- Bucherer reaction.- Bucherer-Bergs reaction.- Buchner-Curtius-Schlotterbeck reaction.- Buchner method of ring expansion.- Buchwald-Hartwig C-N bond and C-O bond formation reactions.- Burgess dehydrating reagent.- Cadiot-Chodkiewicz coupling.- Cannizzaro disproportionation reaction.- Carroll rearrangement.- CastroStephens coupling.- Chapman rearrangement.- Chichibabin amination reaction.- Chichibabin pyridine synthesis.- Chugaev elimination.- CiamicianDennsted rearrangement.- Claisen, Eschenmoser-Claisen, Johnson-Claisen, and Ireland-Claisen rearrangements.- Clark-Eschweiler reductive alkylation of amines.- Combes quinoline synthesis.- Conrad-Lipach reaction.- Cope elimination reaction.- Cope, oxy-Cope, and anionic oxy-Cope rearrangements.- Corey-Chaykovsky epoxidation.- CoreyFuchs reaction.- Corey-Bakshi-Shibata (CBS) reduction.- Corey-Kim oxidation.- Corey-Winter olefin synthesis.- Cornforth rearrangement.- Criegee glycol cleavage.- Criegee mechanism of ozonolysis.- Curtius rearrangement.- Dakin reaction.- Dakin-West reaction.- Danheiser annulation.- Darzens glycidic ester condensation.- Davis chiral oxaziridine reagents.- de Mayo reaction.- Demjanov rearrangement.- Dess-Martin periodinane oxidation.- Dieckmann condensation.- Diels-Alder reaction, inverse electronic demand Diels-Alder reaction, hetero-Diels-Alder reaction.- Dienone-phenol rearrangement.- Di-?-methane rearrangement.- Doebner reaction.- Doebner-von Miller reaction.- Doering-LaFlamme allene synthesis.- Dornow-Wiehler isoxazole synthesis.- Dötz reaction.- Dutt-Wormall reaction.- Eschenmoser coupling reaction.- Eschenmoser-Tanabe fragmentation.- Étard reaction.- Evans aldol reaction.- Favorskii rearrangement and Quasi-Favorskii rearrangement.- Feist-Bénary furan synthesis.- Ferrier rearrangement.- Fischer-Hepp rearrangement.- Fischer indole synthesis.- Fischer-Speier esterification.- Fleming oxidation.- Forster reaction.- Frater-Seebach alkylation.- Friedel-Crafts reaction.- Friedländer synthesis.- Fries rearrangement.- Fritsch-Buttenberg-Wiechell rearrangement.- Fujimoto-Belleau reaction.- Fukuyama amine synthesis.- Gabriel synthesis.- Gassman indole synthesis.- Gattermann-Koch reaction.- Gewald aminothiophene synthesis.- Glaser coupling.- Gomberg-Bachmann reaction.- Gribble indole reduction.- Gribble reduction of diaryl ketones.- Grob fragmentation.- Guareschi-Thorpe condensation.- Hajos-Wiechert reaction.- Haller-Bauer reaction.- Hantzsch pyridine synthesis.- Hantzsch pyrrole synthesis.- Haworth reaction.- Hayashi rearrangement.- Heck reaction.- Hegedus indole synthesis.- Hell-Volhardt-Zelinsky reaction.- Henry reaction (nitroaldol reaction).- Herz reaction.- Heteroaryl Heck reaction.- Hiyama cross-coupling reaction.- HodgesVedejs metallation of oxazoles.- Hofmann rearrangement (Hofmann degradation reaction).- HofmannLöfflerFreytag reaction.- HofmannMartius reaction.- Hooker oxidation.- HornerWadsworthEmmons reaction.- HoubenHoesch reaction.- Hunsdiecker reaction.- Ing-Manske procedure.- Jacobsen-Katsuki epoxidation.- Jacobsen rearrangement.- Japp-Klingemann hydrazone synthesis.- Julia-Lythgoe olefination.- Kahne glycosidation.- Keck stereoselective allylation.- Keck macrolactonization.- Kemp elimination.- Kennedy oxidative cyclization.- Kharasch addition reaction.- Knoevenagel condensation.- Knorr pyrrole synthesis.- Koch carbonylation reaction (Koch-Haaf carbonylation reaction).- Koenig-Knorr glycosidation.- Kolbe-Schmitt reaction.- Kostanecki reaction.- Krapcho decarboxylation.- Kröhnke reaction (pyridine synthesis).- Kumada cross-coupling reaction.- Larock indole synthesis.- Lawesson's reagent.- Leuckart-Wallach reaction.- Lieben haloform reaction.- Liebeskind-Srogl coupling.- Lossen rearrangement.- Luche reduction.- McFadyen-Stevens reduction.- McLafferty fragmentation.- McMurry coupling.- Madelung indole synthesis.- Mannich reaction.- Marshall boronate fragmentation.- Martin's sulfurane dehydrating reagent.- Masamune-Roush conditions.- Meerwein arylation.- Meerwein-Ponndorf-Verley reduction.- Meinwald rearrangement.- Meisenheimer complex.- Meisenheimer rearrangement.- Meyer-Schuster rearrangement.- Michael addition.- Michaelis-Arbuzov phosphonate synthesis.- Midland reduction.- Miller-Snyder aryl cyanide synthesis.- Mislow-Evans rearrangement.- Mitsunobu reaction.- Miyaura boration reaction.- Moffatt oxidation.- Morgan-Walls reaction (Pictet-Hubert reaction).- Mori-Ban indole synthesis.- Morin rearrangement.- Mukaiyama aldol reaction.- Mukaiyama esterification.- Myers-Saito cyclization.- Nametkin rearrangement (Retropinacol rearrangement).- Nazarov cyclization.- Neber rearrangement.- Nef reaction.- Negishi cross-coupling reaction.- Nenitzescu indole synthesis.- Nicholas reaction.- Noyori asymmetric hydrogenation.- Nozaki-Hiyama-Kishi reaction.- Oppenauer oxidation.- Orton rearrangement.- Overman rearrangement.- Paal-Knorr furan synthesis.- Paal-Knorr pyrrole synthesis.- Parham cyclization.- Passerini reaction.- Paterno-Büchi reaction.- Pauson-Khand cyclopentenone synthesis.- Payne rearrangement.- Pechmann condensation (coumarin synthesis).- Pechmann pyrazole synthesis.- Perkin reaction (cinnamic acid synthesis).- Perkow reaction.- Peterson olefination.- Pfau-Plattner azulene synthesis.- Pfitzinger quinoline synthesis.- Pictet-Gams isoquinoline synthesis.- Pictet-Spengler isoquinoline synthesis.- Pinacol rearrangement.- Pinner synthesis.- Polonovski reaction.- Polonovski-Potier reaction.- Pomeranz-Fritsch reaction.- Prévost trans-dihydroxylation.- Prilezhaev reaction.- Prins reaction…