Applied Homogeneous Catalysis

One of the key catalysis books for researchers, professionals in industry, and students, covering homogeneous catalysis from general concepts through detailed examples and industrial applications.

Auteur

Arno Behr headed the Chair of Industrial Chemistry at TU Dortmund University, Germany, until his retirement in 2017. His research interests included homogeneous transition metal catalysis, conversion of petrochemicals and renewables, and catalyst recycling. Thomas Seidensticker leads a research group at TU Dortmund University, Germany. His research is dedicated to sustainable process design for homogeneous catalysts, including developing innovative recycling methods and converting renewable resources. Dieter Vogt is head of the Chair of Industrial Chemistry at TU Dortmund University, Germany, since 2017. His main research interests are homogeneous transition metal catalysis, ligand and catalyst design, and process development in continuously operated miniplants.

Texte du rabat

One-stop reference on homogeneous catalysis, from general concepts through detailed examples and industrial applications Accessible and richly illustrated, Applied Homogeneous Catalysis provides a concise overview of the broad field of homogeneous transition metal catalysis and its applications in the chemical industry. This newly revised and updated second edition puts special emphasis on green chemistry, sustainable resources, and processes. The book is divided into five parts. Part I presents the basics of transition metal catalysis. Part II focuses on process engineering aspects. Part III provides details of the most important catalytic reactions. Part IV describes catalytic conversions closely related to classical homogeneous transition metal catalysis, such as nano-, electro-, photo- and organocatalysis. Part V covers new feedstocks and other topics, concluding with an outlook on future challenges of homogeneous catalysis. The book contains numerous mechanistic details, technical information, and illustrative examples. The chapters are enlivened by various excursions that relate the content to everyday life or introduce important personalities. Didactically, the book is completed with learning objectives and take-home messages for each chapter, as well as more than 400 questions and answers for self-testing. Written by a team of internationally renowned experts in the field, with a wealth of experience in industry and teaching, Applied Homogeneous Catalysis includes information on:

• Economic importance of industrial homogeneously-catalyzed reactions and basics of organometallic chemistry, including types of bonds, elemental steps, and mechanisms
• Common approaches for separating the homogeneous catalyst from the products after the reaction and using combinatorial chemistry and high throughput screening to achieve optimal results
• Activating "inactive" molecules such as carbon dioxide and nitrogen, and harnessing homogeneous catalysis for feedstock diversification by recycling polymers or using renewables. Providing expansive coverage of the subject, Applied Homogeneous Catalysis is an essential guide for Master's and PhD students in organic chemistry, chemical engineering, and related fields, as well as researchers and professionals in the pharmaceutical, polymer, and fine and bulk chemicals industries working on catalysis or entering the field.

Résumé
One of the key catalysis books both for students and researchers as well as professionals in industry, covering homogeneous catalysis from general concepts through detailed examples and industrial applications.

Contenu
FOREWORD
PREFACE
ABBREVIATIONS

INTRODUCTION:
Adhering to the 12 Principles of Green Chemistry: How Does Homogeneous Catalysis Contribute?

PART I: CHEMICAL BASICS

1. Definition, Variants and Examples: What Actually Is Catalysis?
2. A Brief History: Homogeneous Transition Metal Catalysis - A Young Science
3. Industrial Homogeneous Catalysis: What is the Economic Importance?
4. Definition of Important Terms: X, Y, S, STY, TON, TOF and more
5. Basics of Organometallic Chemistry: Bonds, Elementary Steps, and Mechanisms
6. Transition Metal Compounds: The "Captains" of Homogeneous Catalysis
7. Ligands: The "Helmsmen" of Homogeneous Catalysis
8. Solvents in Homogeneous Catalysis: The Reaction Medium
9. Enantioselective Catalysis: The "Special Case"
10. Thermodynamics of Homogeneous Catalysis: When Does a Chemical Reaction Run?
11. Kinetics of Homogeneous Catalysis: How Does the Reaction Proceed?

12. Overview of Spectroscopic Methods: Can We See into Homogeneous Catalysis?

    PART II: PROCESS ENGINEERING FUNDAMENTALS

13. Reactor Types: Where Homogeneous Catalysis Actually Ooccurs
14. Overview of Catalyst Separation Techniques: How Catalyst and Product Go Their Separate Ways After the Reaction
15. Catalyst Separation by Membranes: A Barrier Between Products and Catalysts
16. Immobilisation on Solid Supports: From Homogeneity to Heterogeneity
17. Liquid-Liquid Multiphase Systems: The Smart Approach to Catalyst Separation
18. Switchable Multiphase Systems: Triggering Separation of Homogeneous Mixtures
19. Optimisation Strategies: Combinatorial Synthesis, Design of Experiments and High-Throughput Screening

20. Process Development in Miniplants: From Laboratory to Production

    PART III: HOMOGENEOUSLY CATALYSED REACTION TYPES

21. An Overview of C-C-Bond Formation: A Guide Through the Jungle
22. Hydroformylation: The Industrial Route to Aldehydes and Alcohols
23. Carbonylations: The Versatile Insertions of Carbon Monoxide
24. Oligomerisation and Cyclo-Oligomerisation: The Conversion of Unsaturated Aliphatics into Short Chains or Medium-Sized Ring
25. Metathesis: A "Change-Your-Partners" Dance
26. Polymerisation: The Purposeful Assembly of Macromolecules
27. Telomerisation: The Construction of Functionalised Aliphatic Chains
28. Carbon-Carbon Coupling Reactions: Quite a lot of Name Reactions
29. Hydrogenation: C-H Bond Formation
30. Oxidation: C-O Bond Formation
31. Amination and Hydroamination: C-N Bond Formation
32. Hydrofunctionalisation: Formation of Further C-X Bonds
33. Isomerisation and Rearrangement: Migration of Double Bonds and Rearrangement of the Carbon Backbone

34. Tandem Reactions: Multiple Synthesis Steps in One Pot

    PART IV: ASSOCIATED CATALYSIS

35. Nanocatalysis: A Balancing Act Between Homogeneous and Heterogeneous Catalysis
36. Electrocatalysis: Catalysis with Electrons
37. Photocatalysis: Catalysis with Photons
38. Alternative Ways of Energy Input: Sono-, Microwave- and Mechanocatalysis

39. Organocatalysis: Homogeneous Catalysis only with Organic Compounds

    PART V: NEW RESOURCES

40. Alkane Activation: Acquisition of New Feedstocks
41. Reactions with Carbon Dioxide: Activating an "Inactive" Molecule
42. Nitrogen Activation: Reaching for the Air
43. Recycling of Polymers: The Use of Waste
44. Homogeneous Catalysis with Renewables: Using Nature's Treasures

45. Future Challenges of Homogeneous Catalysis: What the Crystal Ball Might Tell You

    ANSWERS TO THE QUICKIES
    INDEX